If you have an output from the DCC decoder for the coupler that does a momentary pulse in the 1/4 second range, there's an easy way to fire the coupler. Use that pulse to actuate a relay and use track power to fire a PS/1 or Lionel coupler through the relay contacts. Either of these couplers will work fine with 18V as long as you don't leave it on for more than around half a second.
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