Won't work, you'll drop all the voltage across the 22 ohm resistor. The PS/2 couplers get a very short pulse and they draw several amps in order to operate.
I don't think 400ma is enough to operate any coupler. If you really want to use the coupler, you're going to have to add parts, specifically something like a high power FET to actually fire the coupler and use the DCC output to trigger it.