Just took a moment to look over the instruction manual for the SC2 to see if I'm giving you correct information, and I am 99% sure that I am... though from time to time my brain goes out for a sandwich without telling me. Anyway...
you would simply assign one uncoupling track to the through connection and a second one to the throw/curve connection and program them in your remote as a switch. the coupler will fire as long as you hold down the aux1/2 button and otherwise allow you to use the throttle as you can when controlling other switches.
You would call them up by pressing switch instead of accessory.
Edit:
Worth noting that an SC2 can be set up to run 12 Accessories, OR 6 switches, OR 4 switches and 4 accessories, so if you already have more than four normal accessories connected in addition to your uncouplers, this method won't work with just one SC2
JGL